Description
JOHN WILEY Synthesis Of Inorganic Materials 4Th Edition 2019 Edition by Ulrich S. Schubert, Nicola Hüsing
Introduces readers to the field of inorganic materials, while emphasizing synthesis and modification techniquesWritten from the chemist's point of view, this newly updated and completely revised fourth edition of Synthesis of Inorganic Materials provides a thorough and pedagogical introduction to the exciting and fast developing field of inorganic materials and features all of the latest developments. New to this edition is a chapter on self-assembly and self-organization, as well as all-new content on: demixing of glasses, non-classical crystallization, precursor chemistry, citrate-gel and Pechini liquid mix methods, ice-templating, and materials with hierarchical porosity.Synthesis of Inorganic Materials, 4th Edition features chapters covering: solid-state reactions; formation of solids from the gas phase; formation of solids from solutions and melts; preparation and modification of inorganic polymers; self-assembly and self-organization; templated materials; and nanostructured materials. There is also an extensive glossary to help bridge the gap between chemistry, solid state physics and materials science. In addition, a selection of books and review articles is provided at the end of each chapter as a starting point for more in-depth reading. -Gives the students a thorough overview of the fundamentals and the wide variety of different inorganic materials with applications in research as well as in industry-Every chapter is updated with new content-Includes a completely new chapter covering self-assembly and self-organization-Written by well-known and experienced authors who follow an intuitive and pedagogical approachSynthesis of Inorganic Materials, 4th Edition is a valuable resource for advanced undergraduate students as well as masters and graduate students of inorganic chemistry and materials science. Preface ixAcknowledgements xiAbbreviations xv1 Introduction 12 Solid-State Reactions 52.1 Reactions Between Solid Compounds 52.1.1 Ceramic Method 52.1.1.1 General Aspects of Solid-State Reactions 82.1.1.2 Facilitating Solid-State Reactions 122.1.2 Mechanochemical Synthesis 162.1.3 Carbothermal Reduction 172.1.4 Combustion Synthesis 222.1.4.1 Solution Combustion Synthesis 292.2 Solid-Gas Reactions 312.3 Ceramics Processing 342.3.1 Sintering 382.4 Intercalation Reactions 412.4.1 Mechanistic Aspects 472.4.2 Preparative Methods 492.4.3 Intercalation of Polymers in Layered Systems 512.4.4 Pillaring of Layered Compounds 52Further Reading 553 Formation of Solids from the Gas Phase 573.1 Chemical Vapour Transport 573.1.1 Halogen Lamps 593.1.2 Transport Reactions 633.2 Chemical Vapour Deposition 653.2.1 General Aspects 653.2.2 Techniques 733.2.3 Metal CVD 783.2.3.1 Silicon and Aluminium 793.2.3.2 Tungsten 823.2.3.3 Copper 833.2.4 CVD of Carbon 863.2.5 CVD of Binary and Multinary Compounds 893.2.5.1 Metal Oxides 903.2.5.2 Metal Nitrides 923.2.5.3 Metal Chalcogenides and Pnictides 953.2.6 Aerosol-Assisted CVD 973.2.7 Chemical Vapour Infiltration 993.3 Gas-Phase Powder Syntheses 101Further Reading 1104 Formation of Solids from Solutions and Melts 1134.1 Glass 1134.1.1 The Structural Theory of Glass Formation 1154.1.2 Crystallization Versus Glass Formation 1184.1.3 Glass Melting 1234.1.4 Phase Separation 1274.1.5 Metallic Glasses 1284.2 Crystallization from Solution 1324.2.1 Monodispersity 1334.2.2 Shape Control of Crystals 1354.2.3 Non-classical Crystallization 1374.2.4 Biomineralization 1404.2.4.1 Biogenic Materials 1404.2.4.2 Biomineralization 1464.2.4.3 Bioinspired Materials Chemistry 1514.3 Electrodeposition 1564.3.1 Colloids 1564.3.2 Electrodeposition of Ceramics 1594.4 Solvothermal Processes 1614.4.1 Fundamentals 1614.4.2 Growing Single Crystals 1654.4.3 Solvothermal Synthesis 1684.4.3.1 Metal Oxides 1694.4.3.2 Synthetic Calcium Phosphate Biomaterials 1714.4.3.3 Zeolites 1724.5 Sol-Gel Processes 1774.5.1 The Chemistry of Alkoxide Precursors 1814.5.2 Hydrolysis and Condensation 1854.5.2.1 Silica-Based Materials 1864.5.2.2 Metal Oxide-Based Materials 1924.5.3 The Sol-Gel Transition (Gelation) 1954.5.4 Aging and Drying 2014.5.5 Nonhydrolytic Sol-Gel Processes 2034.5.6 Inorganic-Organic Hybrid Materials 2044.5.7 Aerogels 208Further Reading 2145 Preparation and Modification of Inorganic Polymers 2175.1 General Aspects 2185.1.1 Synthesis and Crosslinking 2195.1.2 Copolymers 2215.2 Polysiloxanes (Silicones) 2225.2.1 Properties and Applications 2225.2.2 Structure 2265.2.3 Preparation 2275.2.4 Curing ('Vulcanizing') 2315.3 Polyphosphazenes 2335.3.1 Properties and Applications 2335.3.2 Preparation and Modification 2365.4 Polysilanes 2395.4.1 Properties and Applications 2395.4.2 Preparation 2425.5 Polycarbosilanes 2455.6 Polysilazanes and Related Polymers 2495.7 Polymers with B-N Backbones 2525.8 Other Inorganic Polymers 2535.8.1 Other Phosphorus-Containing Polymers 2545.8.2 Polymers with S-N Backbones 2555.8.3 Metallopolymers 2555.9 Polymer-to-Ceramic Transformation 258Further Reading 2646 Self-Assembly 2676.1 Self-Assembled Monolayers 2686.2 Metal-Organic Frameworks 2716.2.1 Modularity of the Structures 2716.2.2 Synthesis and Modification 2766.3 Supramolecular Arrangements of Surfactants and Block Copolymers 2796.4 Layer-by-Layer Assembly 282Further Reading 2857 Templating 2877.1 Introduction to Porosity and High Surface Area Materials 2897.2 Infiltration and Coating of Templates 2927.2.1 Replica Technique 2937.2.2 Sacrificial Templates 2957.2.2.1 Colloidal Crystals 2967.2.2.2 Hollow Particles 2987.2.3 Direct Foaming 3007.2.4 Nanocasting 3027.3 In Situ Formation of Templates 3057.3.1 Breath Figures 3057.3.2 Freeze Casting 3067.3.3 Supramolecular Assemblies of Amphiphiles 3077.3.3.1 Synthesis of Periodic Mesoporous Silicas 3107.3.3.2 Evaporation-Induced Self-Assembly 3147.3.3.3 Incorporation of Organic Groups 3157.4 Reorganization and Transformation Processes 3177.4.1 Pseudomorphic Transformation 3177.4.2 Kirkendall Effect 3197.4.3 Galvanic Replacement 3207.4.4 Phase Separation and Leaching 321Further Reading 3258 Nanomaterials 3278.1 Properties of Nanomaterials 3298.1.1 Properties Due to Surface Effects 3298.1.2 Properties of Nanocrystalline Materials 3318.1.3 Catalytic Properties 3328.1.4 Optical Properties 3338.1.5 Electrical Properties 3368.1.6 Magnetic Properties 3378.2 Syntheses of Nanoparticles 3398.2.1 Severe Plastic Deformation 3408.2.2 Formation from Vapours 3418.2.3 Formation from Solution 3438.2.4 Surface Modification with Organic Groups 3488.3 One-Dimensional Nanostructures 3528.3.1 Nanowires and Nanorods 3528.3.2 Nanotubes 3578.3.2.1 Carbon Nanotubes 3578.3.2.2 Titania Nanotubes 3628.4 Two-Dimensional Nanomaterials 3658.4.1 Graphene 3658.4.2 Other 2D Nanomaterials 3698.5 Heterostructures and Composites 3708.5.1 Core-Shell Nanoparticles 3708.5.2 Vertical 2D Heterostructures 3738.5.3 Polymer-Matrix Nanocomposites 3748.5.4 Supported Metal Nanoparticles 376Further Reading 378Glossary 381Index 389