Description
Wiley Blackwell Wiley'S Physical Chemistry For Jee (Main & Advanced) 2019 Edition by Wiley Editorial Team
Wiley Physical Chemistry for JEE (Main & Advanced) is a comprehensive text for understanding Physical Chemistry with focus on development of problem-solving skill. The purpose of adaptation of this book is to make the learning experience more complete and help students develop a thought process about a given concept and build an aptitude to apply the same to solve a problem. The adaptation adds the distilled teaching expertise of the author to the original text, supplementing it with additional concepts and solved problems at appropriate places based on his experience of learning pattern of the students and obstacles in their learning curve.
Table of Content:-
1. Basic Concepts and Stoichiometry
1.1 Matter and Its Nature
1.2 Dalton’s Atomic Theory
1.3 Concept of Atom, Molecule, Element and Compound
1.4 Representation of Physical Quantities
1.5 Precision and Accuracy
1.6 Significant Figures
1.7 The International System of Units (S.I.)
1.8 Physical Quantities and Their Measurements
1.9 Dimensional Analysis
1.10 Laws of Chemical Combinations
1.11 Atomic, Molecular and Equivalent Masses
1.12 Mole Concept and Molar Masses
1.13 Percentage Composition
1.14 Empirical and Molecular Formulae
1.15 Chemical Equations and Stoichiometry
1.16 Reactions in Solutions
1.17 Gravimetric Analysis
1.18 Volumetric Analysis
2. Gaseous and Liquid States
2.1 Characteristics of Gases
2.2 Pressure as Measured Property of Gas
2.3 Gas Laws
2.4 Ideal Gas Law
2.5 Graham’s Law of Effusion and Diffusion
2.6 Dalton’s Law of Partial Pressures
2.7 Kinetic Molecular Theory
2.8 Real Gases and Their Deviation from Ideal Gas Behavior
2.9 Compressibility Factor
2.10 Liquefaction of Gases
2.11 Heat Capacity and Specific Heats of Gases
2.12 Liquid State
2.13 Intermolecular Forces in Liquids
2.14 Characteristic Properties of Liquids: Surface Tension and Viscosity
3. Solid State
3.1 Classification of Solids
3.2 Crystal Lattices and Unit Cells
3.3 Calculations Involving Unit Cell Dimensions
3.4 Cubic Lattice – Simple, Face Centered and Body Centered
3.5 Close-Packing in Crystals
3.6 Packing Efficiency and Packing Fraction
3.7 Tetrahedral and Octahedral Voids
3.8 Radius Ratio Rule and Ionic Radius
3.9 X-Ray Diffraction Used to Study Crystal Structures (Bragg’s Law)
3.10 Simple Ionic Compounds
3.11 Defects in Crystals
3.12 Electrical Properties of Solids
3.13 Magnetic Properties of Solids
3.14 Dielectric Properties of Solids
4. Atomic Structure
4.1 Discovery of Electron
4.2 Discovery of Protons and Neutrons
4.3 Atomic Models
4.4 Representation of Atom with Electrons and Nucleons Isobars and Isotopes
4.5 Nature of Electromagnetic Radiations
4.6 Line Spectra of Hydrogen
4.7 Bohr’s Model for Hydrogen Atom
4.8 Dual Nature of Matter
4.9 Quantum Mechanical Model of Atom
4.10 Radial and Angular Wave Functions
4.11 Orbitals and Quantum Numbers
4.12 Rules for Filling of Orbitals in Atom
4.13 Electronic Configuration of Atoms
4.14 Stability of Completely Filled and Half-filled Subshells
4.15 Magnetic Properties
5. Chemical Bonding
5.1 Chemical Bond Formation – Kössel–Lewis Approach
5.2 Lewis Structures of Simple Molecules
5.3 Formal Charge
5.4 Ionic Bonding
5.5 Covalent Bonding
5.6 Coordinate or Dative Bonding
5.7 Resonance Structures
5.8 Exceptions to the Octet Rule
5.9 The Valence Shell Electron Pair Repulsion (VSEPR) Theory and Shapes of Simple Molecules
5.10 Quantum Mechanical Theory of Chemical Bonding
5.11 Valence Bond Theory
5.12 Hybridization
5.13 Molecular Orbital Theory
5.14 Concept of Bond Order, Bond Length and Bond Energy
5.15 Bonding in Some Homonuclear Diatomic Molecules
5.16 Heteronuclear Diatomic Molecules
5.17 Back Bonding
5.18 Elementary Idea of Metallic Bonding
5.19 Hydrogen Bonding
6. Thermodynamics
6.1 Fundamentals of Thermodynamics
6.2 The Zeroth Law of Thermodynamics
6.3 Energy of the Thermodynamic System
6.4 The First Law of Thermodynamics
6.5 Interpretation of First Law of Thermodynamics
6.6 Enthalpy or Heat Content, H
6.7 Heat Capacity
6.8 Expansion and Compression of an Ideal Gas
6.9 Joule–Thomson Effect and Inversion Temperature
6.10 Calorimetry
6.11 Thermochemistry
6.12 Thermochemical Equations
6.13 Laws of Thermochemistry
6.14 Enthalpies of Different Types of Reactions
6.15 Bond Enthalpy and Bond Dissociation Enthalpies
6.16 Spontaneity
6.17 Entropy and Spontaneity
6.18 Gibbs Energy and Spontaneity
6.19 Second Law of Thermodynamics
6.20 Gibbs Energy Change and Equilibrium
6.21 Carnot Cycle
6.22 Third Law of Thermodynamics
7. Solutions
7.1 Type of Solutions
7.2 Solubility
7.3 Effect of Nature of Solute and Solvent
7.4 Effect of Temperature on Solubility
7.5 Effect of Pressure on Solubility of Gases
7.6 Different Methods for Expressing Concentration of Solution
7.7 Vapor Pressure of Solutions
7.8 Enthalpy of Solution
7.9 Ideal Solutions
7.10 Non-Ideal Solutions
7.11 Colligative Properties and Determination of Molar Mass
7.12 Abnormal Molar Masses and van′t Hoff Factor
8. Chemical Equilibrium
8.1 Physical Equilibria
8.2 Chemical Equilibria – Dynamic Equilibrium
8.3 Law of Chemical Equilibrium and Equilibrium Constant
8.4 Homogeneous and Heterogeneous Equlibria
8.5 Applications of Equilibrium Constants
8.6 Gibbs Energy Change and Chemical Equilibrium
8.7 Le Chatelier’s Principle and Factors Affecting Equilibria
9. Ionic Equilibrium
9.1 Weak and Strong Electrolytes
9.2 Ionization of Electrolytes
9.3 Concepts of Acids and Bases
9.4 Ionization of Acids and Bases or Acid–Base Equilibria and Ionization Constants
9.5 Relative Strength of Acids and Bases
9.6 Ionization of Polyprotic Acids
9.7 Factors Affecting Acid Strength
9.8 Acid–Base Neutralization-Formation of Salts
9.9 Ionic Product of Water
9.10 pH Concept
9.11 Solving Acid–Base Equilibria Problems
9.12 Common Ion Effect in the Ionization of Acids and Bases
9.13 Hydrolysis of Salts and the pH of their Solutions
9.14 Buffer Solutions
9.15 Solubility Equilibria of Sparingly Soluble Salts
9.16 Preferential Precipitation of Salts
9.17 Applications of Solubility Product
9.18 Theory of Indicators
9.19 Acid–Base Titrations
10. Redox Reactions
10.1 Classical Concept of Oxidation and Reduction
10.2 Oxidation and Reduction as Electron Transfer Reactions
10.3 Displacement Reactions and Activity Series
10.4 Oxidation Number and Oxidation State
10.5 Types of Redox Reactions
10.6 Balancing of Redox Reactions
10.7 Applications of Redox Reactions
10.8 Redox Titrations
10.9 Stoichiometry of Redox Reactions and Concept of Gram Equivalents
11. Electrochemistry
11.1 Electrical Conductance
11.2 Conductance in Solutions of Electrolytes
11.3 Kohlrausch’s Law
11.4 Conductometric Titrations
11.5 Electrochemical Cells
11.6 Electrode Potential
11.7 Measurement of Electrode Potential
11.8 Thermodynamics of a Cell
11.9 Nernst Equation
11.10 Types of Electrodes
11.11 Concentration Cells
11.12 Electrolytic Cells and Electrolysis
11.13 Applications of Electrolytic Process
11.14 Batteries
11.15 Fuel Cells
12. Chemical Kinetics
12.1 Rate of a Chemical Reaction
12.2 Factors Influencing Rate of a Reaction
12.3 Differential Rate Expression and Rate Constant
12.4 Elementary and Complex Reactions
12.5 Molecularity of a Reaction
12.6 Order of a Reaction
12.7 Calculations of Order and Molecularity Based on Reaction Mechanisms
12.8 Pseudo Order Reactions
12.9 Integrated Rate Equations
12.10 Half-Life of Reactions and Radioactivity
12.11 Derivation of Rate Laws for Complex Reactions Using Integrated Rate Equations
12.12 Determination of Order of Simple Reactions – Experimental Methods
12.13 Effect of Temperature – Arrhenius Theory
12.14 Effect of Catalyst
12.15 Collision Theory
13. Surface Chemistry
13.1 Adsorption
13.2 Factors Affecting Adsorption
13.3 Adsorption Isotherms
13.4 Some Applications of Adsorption
13.5 Catalysis
13.6 Types of Catalytic Reactions
13.7 Theory of Heterogeneous Catalysis
13.8 Shape-Selective Catalysis by Zeolites
13.9 Enzyme Catalysis
13.10 Catalysts in Industry
13.11 Colloids
13.12 Preparation of Colloids
13.13 Purification of Colloidal Solutions
13.14 Properties of Colloidal Solutions
13.15 Coagulation or Precipitation and Hardy–Schulze Rule
13.16 Protection of Colloids
13.17 Emulsions
13.18 Role of Colloids in Natural Phenomena and in Industry
14. Nuclear Chemistry
14.1 Radioactivity
14.2 Structure of Atom
14.3 Stability of Nucleus
14.4 Modes of Radioactive Decay
14.5 Decay Mechanism in Neutron-Rich and Neutron-Poor Nuclides
14.6 Binding Energy and Nuclear Stability
14.7 The Kinetics of Radioactive Decay
14.8 Radioactive Equilibrium
14.9 Activity of Radioactive Substances, Detection and Units of Radioactivity
14.10 Natural vs. Induced Radioactivity
14.11 Transmutation
14.12 Nuclear Reactions
14.13 Biological Effect of Radiation
14.14 Applications of Radioactivity
Solved Objective Questions from Previous Year Papers
Review Questions
Numerical Problems
Additional Objective Questions
Answers
JEE (Main) Chemistry Paper
JEE (Advanced) Chemistry Paper
Index