Description
Wiley Wiley'S Physical Chemistry For Jee (Main & Advanced), 2019Ed by Vipul Mehta
Wiley Physical Chemistry for JEE (Main & Advanced) is a comprehensive text for understanding Physical Chemistry with focus on development of problem-solving skills. This adaptation of the book aims to enhance the learning experience of the book, deriving advantage from the adapting author's experience with learning pattern of the students and obstacles in their learning curve. The premise is to encourage self-study in students and help them develop understanding of the concept and build an aptitude to apply the same learning to solve a problem.
Table of Contents
1. Mole Concept–I
1.1 Basic Concepts
1.2 Mole – Basic Introduction
1.3 Percentage Composition
1.4 Mole Concept – Stoichiometry
1.5 Principle of Atom Conservation (POAC)
1.6 Concentration Terms
1.7 Miscellaneous Application of Mole Concept: Gravimetric Analysis
2. Mole Concept–II
2.1 Oxidation Number Concept
2.2 Oxidation and Reduction
2.3 Calculation of n-Factor in a Reaction
2.4 Balancing of Redox Reactions
2.5 Concept of Equivalent Mass
2.6 Stoichiometry of Redox Reactions and Concept of Gram Equivalents
2.7 Volumetric Analysis
2.8 Types of Titrations
2.9 Applications of Redox Reactions
3. Gaseous and Liquid States
3.1 Characteristics of Gases
3.2 Pressure as Measured Property of Gas
3.3 Gas Laws
3.4 Ideal Gas Law
3.5 Payload
3.6 Variation of Pressure with Change in Density of Fluid
3.7 Faulty Barometer
3.8 Dalton’s Law of Partial Pressures
3.9 Graham’s Law of Effusion and Diffusion
3.10 Kinetic Theory of Gases
3.11 Molecular Collisions
3.12 Real Gases and Their Deviation from Ideal Gas Behavior
3.13 Compressibility Factor
3.14 Liquefaction of Gases
3.15 Law of Corresponding States
3.16 Heat Capacity and Specific Heats of Gases
3.17 Liquid State
3.18 Intermolecular Forces in Liquids
3.19 Characteristic Properties of Liquids: Surface Tension and Viscosity
4. Solid State
4.1 Classification of Solids
4.2 Crystal Lattices and Unit Cells
4.3 Calculations Involving Unit Cell Dimensions
4.4 Cubic Lattice – Simple, Face Centered and Body Centered
4.5 Close-Packing in Crystals
4.6 Packing Efficiency and Packing Fraction
4.7 Tetrahedral and Octahedral Voids
4.8 Radius Ratio Rule and Ionic Radius
4.9 Simple Ionic Compounds
4.10 X-Ray Diffraction Used to Study Crystal Structures (Bragg’s Law)
4.11 Defects in Crystals
4.12 Electrical Properties of Solids
4.13 Magnetic Properties of Solids
4.14 Dielectric Properties of Solids
5. Atomic Structure
5.1 Discovery of Electron
5.2 Discovery of Protons and Neutrons
5.3 Some Prerequisites of Physics
5.4 Atomic Models
5.5 Representation of Atom with Electrons and Neutrons
5.6 Nature of Waves
5.7 Nature of Electromagnetic Radiation
5.8 Planck’s Quantum Theory
5.9 Spectra – Continuous and Discontinuous Spectrum
5.10 Bohr’s Model for Hydrogen Atom
5.11 Photoelectric Effect
5.12 Dual Nature of Matter
5.13 Heisenberg’s Uncertainty Principle
5.14 Number of Waves Made by the Electron
5.15 Quantum Mechanical Model of Atom
5.16 Radial and Angular Wave Functions
5.17 Orbitals and Quantum Numbers
5.18 Electronic Configuration of Atoms
5.19 Magnetic Properties
6. Chemical Bonding
6.1 Chemical Bond Formation – Kössel–Lewis Approach
6.2 Lewis Structures of Simple Molecules
6.3 Formal Charge
6.4 Covalent Bonding
6.5 Coordinate or Dative Bonding
6.6 Valence Bond Theory
6.7 Hybridization
6.8 The Valence Shell Electron Pair Repulsion (VSEPR) Theory and Shapes of Simple Molecules
6.9 Back Bonding
6.10 Ionic Bonding
6.11 Dipole Moment
6.12 Resonance Structures
6.13 Hydrogen Bonding
6.14 Molecular Orbital Theory
6.15 Concept of Bond Order, Bond Length and Bond Energy
6.16 Bonding in Some Homonuclear Diatomic Molecules
6.17 Heteronuclear Diatomic Molecules
6.18 Elementary Idea of Metallic Bonding
6.19 Weak Forces
6.20 Interactions between Ions and Covalent Molecules
7. Chemical Energetics
7.1 Fundamentals of Thermodynamics
7.2 The Zeroth Law of Thermodynamics
7.3 Energy of the Thermodynamic System
7.4 The First Law of Thermodynamics
7.5 Calculation of Work Done in Different Processes
7.6 Enthalpy or Heat Content, H
7.7 Expansion and Compression of an Ideal Gas
7.8 Joule–Thomson Effect and Inversion Temperature
7.9 Calorimetry
7.11 Thermochemical Equations
7.12 Laws of Thermochemistry
7.13 Enthalpies of Different Types of Reactions
7.14 Bond Enthalpy and Bond Dissociation Enthalpy
7.15 Spontaneity
7.16 Carnot Cycle
7.17 Entropy and Spontaneity
7.18 Gibbs Energy and Spontaneity
7.19 Second Law of Thermodynamics
7.20 Gibbs Energy Change and Equilibrium
7.21 Third Law of Thermodynamics
8. Solutions
8.1 Type of Solutions
8.2 Solubility
8.3 Effect of Nature of Solute and Solvent
8.4 Effect of Temperature on Solubility
8.5 Effect of Pressure on Solubility of Gases
8.6 Different Methods for Expressing Concentration of Solution
8.7 Vapor Pressure of Solutions
8.8 Enthalpy of Solution
8.9 Ideal Solutions
8.10 Non-Ideal Solutions
8.11 Colligative Properties and Determination of
8.12 Abnormal Molar Masses and van ’t Hoff Factor
9. Chemical Equilibrium
9.1 Physical Equilibria
9.2 Chemical Equilibria – Dynamic Equilibrium
9.3 Law of Chemical Equilibrium and Equilibrium
9.4 Homogeneous and Heterogeneous Equilibria
9.5 Applications of Equilibrium Constants
9.6 Gibbs Energy Change and Chemical Equilibrium
9.7 Simultaneous Equilibrium
9.8 Le Chatelier’s Principle and Factors Affecting Equilibria
10. Ionic Equilibrium
10.1 Weak and Strong Electrolytes
10.2 Ionization of Electrolytes
10.3 Concepts of Acids and Bases
10.4 Acid–Base Equilibria and Ionization Constants
10.5 Relative Strength of Acids and Bases
10.6 Ionization of Polyprotic Acids
10.7 Factors Affecting Acid Strength
10.8 Acid–Base Neutralization – Formation of Salts
10.9 pH Calculation of Single Monobasic Acid or Monoacidic Base
10.10 pH Calculation of a Mixture of Two Acids or Bases
10.11 pH Calculation for Polyprotic Acids
10.12 Hydrolysis of Salts and pH of Their Solutions
10.13 Buffer Solutions
10.14 Acid–Base Titrations
10.15 Theory of Indicators
10.16 Solubility Equilibria of Sparingly Soluble Salts
10.17 Preferential Precipitation of Salts
10.18 Applications of Solubility Product
11. Electrochemistry
11.1 Electrochemical Cells
11.2 Electrode Potential
11.3 Measurement of Electrode Potential
11.4 Thermodynamics of a Cell
11.5 Nernst Equation
11.6 Calculation of E°cell
11.7 Types of Electrodes
11.8 Concentration Cells
11.9 Electrolytic Cells and Electrolysis
11.10 Applications of Electrolytic Process
11.11 Batteries
11.12 Electrical Conductance
11.13 Conductance in Solutions of Electrolytes
11.14 Conductometric Titrations
12. Chemical Kinetics
12.1 Rate of a Chemical Reaction
12.2 Factors Influencing Rate of a Reaction
12.3 Differential Rate Expression and Rate Constant
12.4 Elementary and Complex Reactions
12.5 Molecularity of a Reaction
12.6 Order of a Reaction
12.7 Calculations of Order and Molecularity Based on Reaction Mechanisms
12.8 Pseudo Order Reactions
12.9 Integrated Rate Equations
12.10 Half-Life of Reactions and Radioactivity
12.11 Derivation of Rate Laws for Complex Reactions Using Integrated Rate Equations
12.12 Determination of Order of Simple Reactions – Experimental Methods
12.13 Effect of Temperature – Arrhenius Theory
12.14 Effect of Catalyst
12.15 Collision Theory
13. Surface Chemistry
13.1 Adsorption
13.2 Factors Affecting Adsorption
13.3 Adsorption Isotherms
13.4 Some Applications of Adsorption
13.5 Catalysis
13.6 Types of Catalytic Reactions
13.7 Theory of Heterogeneous Catalysis
13.8 Shape-Selective Catalysis by Zeolites
13.9 Enzyme Catalysis
13.10 Catalysts in Industry
13.11 Colloids
13.12 Preparation of Colloids
13.13 Purification of Colloidal Solutions
13.14 Properties of Colloidal Solutions
13.15 Coagulation or Precipitation and Hardy–Schulze Rule
13.16 Protection of Colloids
13.17 Emulsions
13.18 Role of Colloids in Natural Phenomena and in Industry
14 Nuclear Chemistry
14.1 Radioactivity
14.2 Structure of Atom
14.3 Stability of Nucleus
14.4 Modes of Radioactive Decay
14.5 Decay Mechanism in Neutron-Rich and Neutron-Poor Nuclides
14.6 Binding Energy and Nuclear Stability
14.7 The Kinetics of Radioactive Decay
14.8 Radioactive Equilibrium
14.9 Activity of Radioactive Substances, Detection and Units of Radioactivity
14.10 Natural vs. Induced Radioactivity
14.11 Transmutation
14.12 Nuclear Reactions
14.13 Biological Effects of Radiation
14.14 Applications of Radioactivity
Solved Objective Questions from Previous Year Papers
Review Questions
Numerical Problems
Additional Objective Questions
Answers
Appendix A
Appendix B
JEE (Main) Paper
JEE (Advanced) Paper
Index