Organic Coatings Science And Technology by Zeno W. Wicks , John Wiley and Sons Ltd

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John Wiley and Sons Ltd Organic Coatings Science And Technology by Zeno W. Wicks

Third Edition brings acclaimed textthoroughly up to date with the latestorganic coatings technology _x000D_Organic Coatings, Third Edition is an unparalleled reference and text for organic coatings technology and its myriad applications. It begins with discussions of key principles of coatings, then thoroughly explores raw materials, physical concepts, formulations, and applications. Scientists, engineers, and paint formulators all gain a deeper understanding of the principles underlying the technology and learn how to use these principles in the development, production, and application of organic coatings. The four authors, all leading industry experts, offer a unique approach to the topic that correlates the empirical technology of coatings with the underlying science. _x000D_This Third Edition has been completely revised and updated to reflect numerous changes in the field, including changes driven by increasing pressure to lower VOC emissions, reduce energy requirements, and eliminate potential health hazards from organic coatings components. In addition, the authors have developed new material to make the text more accessible for scientists and engineers first entering the field, as well as for students taking coatings courses. At the same time, the hallmarks that distinguished the two previous editions have been retained, including: _x000D_Troubleshooting guidance for coatings scientists and technologistsClear differentiation between established principles and hypotheses requiring further researchPrecise definitions of coatings industry terminologyExtensive references to the current literatureHundreds of figures that help readers visualize key concepts and techniques _x000D_Whether you are just entering the field of organic coatings and need a broad overview or you are an experienced professional who needs a sophisticated reference, you can depend on Organic Coatings to give you the information and answers you need._x000D_ _x000D_ Preface. _x000D_ Symbols and Units. _x000D_ 1. What Are Coatings? _x000D_ 1.1. Definitions and Scope. _x000D_ 1.2. Composition of Coatings. _x000D_ References. _x000D_ 2. Polymerization and Film Formation. _x000D_ 2.1. Polymers. _x000D_ 2.2. Polymerization. _x000D_ 2.3. Film Formation. _x000D_ General References. _x000D_ References. _x000D_ 3. Flow. _x000D_ 3.1. Shear Flow. _x000D_ 3.2. Types of Shear Flow. _x000D_ 3.3. Determination of Shear Viscosity. _x000D_ 3.4. Shear Viscosity of Resin Solutions. _x000D_ 3.5. Viscosity of Liquids with Dispersed Phases. _x000D_ 3.6. Other Modes of Flow. _x000D_ General References. _x000D_ References. _x000D_ 4. Mechanical Properties. _x000D_ 4.1. Introduction: General Comments on Testing of Coating Films. _x000D_ 4.2. Basic Mechanical Properties. _x000D_ 4.3. Formability and Flexibility. _x000D_ 4.4. Abrasion and Mar Resistance. _x000D_ 4.5. Measurement of Mechanical Properties. _x000D_ 4.6. Tests of Coatings on Substrates. _x000D_ General References. _x000D_ References. _x000D_ 5. Exterior Durability. _x000D_ 5.1. Photoinitiated Oxidative Degradation. _x000D_ 5.2. Photostabilization. _x000D_ 5.3. Degradation of Chlorinated Resins. _x000D_ 5.4. Hydrolytic Degradation. _x000D_ 5.5. Other Modes of Failure on Exterior Exposure. _x000D_ 5.6. Testing for Exterior Durability. _x000D_ General References. _x000D_ References. _x000D_ 6. Adhesion. _x000D_ 6.1. Surface Mechanical Effects on Adhesion. _x000D_ 6.2. Effects of Internal Stress and Fracture Mechanics. _x000D_ 6.3. Relationship Between Wetting and Adhesion. _x000D_ 6.4. Adhesion to Metal Surfaces. _x000D_ 6.5. Adhesion to Plastics and to Coatings. _x000D_ 6.6. Testing for Adhesion. _x000D_ General References. _x000D_ References. _x000D_ 7. Corrosion Protection by Coatings. _x000D_ 7.1. Corrosion of Uncoated Steel. _x000D_ 7.2. Corrosion Protection of Metals. _x000D_ 7.3. Corrosion Protection by Intact Coatings. _x000D_ 7.4. Corrosion Protection by Nonintact Films. _x000D_ 7.5. Evaluation and Testing. _x000D_ General References. _x000D_ References. _x000D_ 8. Acrylic Resins. _x000D_ 8.1. Thermoplastic Acrylic Resins. _x000D_ 8.2. Thermosetting Acrylic Resins. _x000D_ 8.3. Water-Reducible Thermosetting Acrylic Resins. _x000D_ References. _x000D_ 9. Latexes. _x000D_ 9.1. Emulsion Polymerization. _x000D_ 9.2. Acrylic Latexes. _x000D_ 9.3. Vinyl Ester Latexes. _x000D_ 9.4. Thermosetting Latexes. _x000D_ General References. _x000D_ References. _x000D_ 10. Polyester Resins. _x000D_ 10.1. Hydroxy-Terminated Polyester Resins for Conventional Solids Coatings. _x000D_ 10.2. Polyester Resins for High-Solids Coatings. _x000D_ 10.3. Carboxylic Acid Terminated Polyester Resins. _x000D_ 10.4. Carbamate-Functional Polyester Resins. _x000D_ 10.5. Water-Reducible Polyester Resins. _x000D_ 10.6. Polyester Resins for Powder Coatings. _x000D_ References / 211 _x000D_ 11. Amino Resins. _x000D_ 11.1. Synthesis of Melamine Formaldehyde Resins. _x000D_ 11.2. Types of MF Resins. _x000D_ 11.3. MF Polyol Reactions in Coatings. _x000D_ 11.4. Other Amino Resins. _x000D_ References. _x000D_ 12. Binders Based on Polyisocyanates: Polyurethanes. _x000D_ 12.1. Reactions of Isocyanates. _x000D_ 12.2. Kinetics of Reactions of Isocyanates with Alcohols. _x000D_ 12.3. Isocyanates Used in Coatings. _x000D_ 12.4. Two Package Solventborne Urethane Coatings. _x000D_ 12.5. Blocked Isocyanates. _x000D_ 12.6. Moisture-Curable Urethane Coatings. _x000D_ 12.7. Waterborne Urethane Coatings. _x000D_ 12.8. Hydroxy-Terminated Polyurethanes. _x000D_ References. _x000D_ 13. Epoxy and Phenolic Resins. _x000D_ 13.1. Epoxy Resins. _x000D_ 13.2. Epoxy Amine Systems. _x000D_ 13.3. Other Cross-Linking Agents for Epoxy Resins. _x000D_ 13.4. Water-Reducible Epoxy Acrylic Graft Copolymers. _x000D_ 13.5. Epoxy Resin Phosphate Esters. _x000D_ 13.6. Phenolic Resins. _x000D_ General References. _x000D_ References. _x000D_ 14. Drying Oils. _x000D_ 14.1. Composition of Natural Oils. _x000D_ 14.2. Autoxidation and Cross-Linking. _x000D_ 14.3. Synthetic and Modified Drying Oils. _x000D_ General References. _x000D_ References. _x000D_ 15. Alkyd Resins. _x000D_ 15.1. Oxidizing Alkyds. _x000D_ 15.2. High-Solids Oxidizing Alkyds. _x000D_ 15.3. Water-Reducible Alkyds. _x000D_ 15.4. Nonoxidizing Alkyds. _x000D_ 15.5. Synthetic Procedures for Alkyd Resins. _x000D_ 15.6. Modified Alkyds. _x000D_ 15.7. Uralkyds and Other Autoxidizable Urethanes. _x000D_ 15.8. Epoxy Esters. _x000D_ General Reference. _x000D_ References. _x000D_ 16. Silicon Derivatives. _x000D_ 16.1. Silicones. _x000D_ 16.2. Reactive Silanes. _x000D_ 16.3. Orthosilicates. _x000D_ References. _x000D_ 17. Other Resins and Cross-Linkers. _x000D_ 17.1. Halogenated Polymers. _x000D_ 17.2. Cellulose Derivatives. _x000D_ 17.3. Unsaturated Polyester Resins. _x000D_ 17.4. (Meth)acrylated Oligomers. _x000D_ 17.5. 2-Hydroxyalkylamide Cross-Linkers. _x000D_ 17.6. Acetoacetate Cross-Linking Systems. _x000D_ 17.7. Polyaziridine Cross-Linkers. _x000D_ 17.8. Polycarbodiimide Cross-Linkers. _x000D_ 17.9. Polycarbonates. _x000D_ References. _x000D_ 18. Solvents. _x000D_ 18.1. Solvent Composition. _x000D_ 18.2. Solubility. _x000D_ 18.3. Solvent Evaporation Rates. _x000D_ 18.4. Viscosity Effects. _x000D_ 18.5. Flammability. _x000D_ 18.6. Other Physical Properties. _x000D_ 18.7. Toxic Hazards. _x000D_ 18.8. Atmospheric Photochemical Effects. _x000D_ 18.9. Regulation of Solvent Emissions from Coatings. _x000D_ General References. _x000D_ References. _x000D_ 19. Color and Appearance. _x000D_ 19.1. Light. _x000D_ 19.2. Light Object Interactions. _x000D_ 19.3. Hiding. _x000D_ 19.4. Metallic and Interference Colors. _x000D_ 19.5. The Observer. _x000D_ 19.6. Interactions of Light Source, Object, and Observer. _x000D_ 19.7. Color Systems. _x000D_ 19.8. Color Mixing. _x000D_ 19.9. Color Matching. _x000D_ 19.10. Gloss. _x000D_ General References. _x000D_ References. _x000D_ 20. Pigments. _x000D_ 20.1. White Pigments. _x000D_ 20.2. Color Pigments. _x000D_ 20.3. Inert Pigments. _x000D_ 20.4. Functional Pigments. _x000D_ 20.5. Nano-pigments. _x000D_ General References. _x000D_ References. _x000D_ 21. Pigment Dispersion. _x000D_ 21.1. Dispersion in Organic Media. _x000D_ 21.2. Formulation of Non-aqueous Mill Bases. _x000D_ 21.3. Dispersions in Aqueous Media. _x000D_ 21.4. Dispersion Equipment and Processes. _x000D_ 21.5. Evaluation of Dispersion. _x000D_ General References. _x000D_ References. _x000D_ 22. Effect of Pigments on Coating Properties. _x000D_ 22.1. PVC and CPVC. _x000D_ 22.2. Relationships Between Film Properties and PVC. _x000D_ References. _x000D_ 23. Application Methods. _x000D_ 23.1. Brushes, Pads, and Hand Rollers. _x000D_ 23.2. Spray Application. _x000D_ 23.3. Dip and Flow Coating. _x000D_ 23.4. Roll Coating. _x000D_ 23.5. Curtain Coating. _x000D_ General References. _x000D_ References. _x000D_ 24. Film Defects. _x000D_ 24.1. Surface Tension. _x000D_ 24.2. Leveling. _x000D_ 24.3. Sagging and Drip Marks. _x000D_ 24.4. Crawling, Cratering, and Related Defects. _x000D_ 24.5. Floating and Flooding; Hammer Finishes. _x000D_ 24.6. Wrinkling and Wrinkle Finishes. _x000D_ 24.7. Bubbling and Popping. _x000D_ 24.8. Foaming. _x000D_ 24.9. Dirt. _x000D_ General References. _x000D_ References. _x000D_ 25. Solventborne and High-Solids Coatings. _x000D_ 25.1. Primers. _x000D_ 25.2. Top Coats. _x000D_ General Reference. _x000D_ References. _x000D_ 26. Waterborne Coatings. _x000D_ 26.1. Water-Reducible Coatings. _x000D_ 26.2. Latex-Based Coatings. _x000D_ 26.3. Emulsion Coatings. _x000D_ General References. _x000D_ References. _x000D_ 27. Electrodeposition Coatings. _x000D_ 27.1. Anionic Electrodeposition Coatings. _x000D_ 27.2. Cationic Electrodeposition Coatings. _x000D_ 27.3. Effect of Variables on Electrodeposition. _x000D_ 27.4. Application of Electrodeposition Coatings. _x000D_ 27.5. Advantages and Limitations of Electrodeposition. _x000D_ 27.6. Autodeposition Coatings. _x000D_ General Reference. _x000D_ References. _x000D_ 28. Powder Coatings. _x000D_ 28.1. Binders for Thermosetting Powder Coatings. _x000D_ 28.2. Binders for Thermoplastic Powder Coatings. _x000D_ 28.3. Formulation of Thermosetting Powder Coatings. _x000D_ 28.4. Manufacture of Powder Coatings. _x000D_ 28.5. Application Methods. _x000D_ 28.6. Advantages and Limitations of Powder Coatings. _x000D_ General References. _x000D_ References. _x000D_ 29. Radiation Cure Coatings. _x000D_ 29.1. UV Curing. _x000D_ 29.2. Free Radical Initiated UV Cure. _x000D_ 29.3. Cationic UV Cure. _x000D_ 29.4. Effects of Pigmentation. _x000D_ 29.5. Electron Beam Cure Coatings. _x000D_ 29.6. Dual UV/Thermal Cure and Selected Applications. _x000D_ 29.7. Advantages and Limitations. _x000D_ General References. _x000D_ References. _x000D_ 30. Product Coatings for Metal Substrates. _x000D_ 30.1. OEM Automotive Coatings. _x000D_ 30.2. Appliance Coatings. _x000D_ 30.3. Container Coatings. _x000D_ 30.4. Coil Coating. _x000D_ General References. _x000D_ References. _x000D_ 31. Product Coatings for Nonmetallic Substrates. _x000D_ 31.1. Coatings for Wood. _x000D_ 31.2. Coating of Plastics. _x000D_ 31.3. Coatings for Glass. _x000D_ General Reference. _x000D_ References. _x000D_ 32. Architectural Coatings. _x000D_ 32.1. Exterior House Paint. _x000D_ 32.2. Flat and Semigloss Paints. _x000D_ 32.3. Gloss Enamels. _x000D_ General Reference. _x000D_ References. _x000D_ 33. Special Purpose Coatings. _x000D_ 33.1. Maintenance Paints. _x000D_ 33.2. Marine Coatings. _x000D_ 33.3. Automobile Refinish Paints. _x000D_ 33.4. Aircraft Coatings. _x000D_ References. _x000D_ 34. Perspectives on Coating Design. _x000D_ General References. _x000D_ References. _x000D_ Index._x000D_