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WILEY INDIA Wiley'S Physical Chemistry For Jee (Main & Advanced) 2021 by Vipul Mehta
Wiley Physical Chemistry for JEE (Main & Advanced) is a comprehensive text for understanding Physical Chemistry with focus on development of problem-solving skills. This adaptation of the book aims to enhance the learning experience of the book, deriving advantage from the adapting author's experience with learning pattern of the students and obstacles in their learning curve. The premise is to encourage self-study in students and help them develop understanding of the concept and build an aptitude to apply the same learning to solve a problem. 1. Mole Concept–I1.1 Basic Concepts1.2 Mole – Basic Introduction1.3 Percentage Composition1.4 Mole Concept – Stoichiometry1.5 Principle of Atom Conservation (POAC)1.6 Concentration Terms1.7 Miscellaneous Application of Mole Concept: Gravimetric Analysis 2. Mole Concept–II2.1 Oxidation Number Concept2.2 Oxidation and Reduction2.3 Calculation of -Factor in a Reaction2.4 Balancing of Redox Reactions2.5 Concept of Equivalent Mass2.6 Stoichiometry of Redox Reactions and Concept of Gram Equivalents2.7 Volumetric Analysis2.8 Types of Titrations2.9 Applications of Redox Reactions 3. Gaseous and Liquid States3.1 Characteristics of Gases3.2 Pressure as Measured Property of Gas3.3 Gas Laws3.4 Ideal Gas Law3.5 Payload3.6 Variation of Pressure with Change in Density of Fluid3.7 Faulty Barometer3.8 Dalton’s Law of Partial Pressures3.9 Graham’s Law of Effusion and Diffusion3.10 Kinetic Theory of Gases3.11 Molecular Collisions3.12 Real Gases and Their Deviation from Ideal Gas Behavior3.13 Compressibility Factor3.14 Liquefaction of Gases3.15 Law of Corresponding States3.16 Heat Capacity and Specific Heats of Gases3.17 Liquid State3.18 Intermolecular Forces in Liquids3.19 Characteristic Properties of Liquids: Surface Tension and Viscosity 4. Solid State4.1 Classification of Solids4.2 Crystal Lattices and Unit Cells4.3 Calculations Involving Unit Cell Dimensions4.4 Cubic Lattice – Simple, Face Centered and Body Centered4.5 Close-Packing in Crystals4.6 Packing Efficiency and Packing Fraction4.7 Tetrahedral and Octahedral Voids4.8 Radius Ratio Rule and Ionic Radius4.9 Simple Ionic Compounds4.10 X-Ray Diffraction Used to Study Crystal Structures (Bragg’s Law)4.11 Defects in Crystals4.12 Electrical Properties of Solids4.13 Magnetic Properties of Solids4.14 Dielectric Properties of Solids 5. Atomic Structure5.1 Discovery of Electron5.2 Discovery of Protons and Neutrons5.3 Some Prerequisites of Physics5.4 Atomic Models5.5 Representation of Atom with Electrons and Neutrons5.6 Nature of Waves5.7 Nature of Electromagnetic Radiation5.8 Planck’s Quantum Theory5.9 Spectra – Continuous and Discontinuous Spectrum5.10 Bohr’s Model for Hydrogen Atom5.11 Photoelectric Effect5.12 Dual Nature of Matter5.13 Heisenberg’s Uncertainty Principle5.14 Number of Waves Made by the Electron5.15 Quantum Mechanical Model of Atom5.16 Radial and Angular Wave Functions5.17 Orbitals and Quantum Numbers5.18 Electronic Configuration of Atoms5.19 Magnetic Properties 6. Chemical Bonding6.1 Chemical Bond Formation – Kössel–Lewis Approach6.2 Lewis Structures of Simple Molecules6.3 Formal Charge6.4 Covalent Bonding6.5 Coordinate or Dative Bonding6.6 Valence Bond Theory6.7 Hybridization6.8 The Valence Shell Electron Pair Repulsion (VSEPR) Theory and Shapes of Simple Molecules6.9 Back Bonding6.10 Ionic Bonding6.11 Dipole Moment6.12 Resonance Structures6.13 Hydrogen Bonding6.14 Molecular Orbital Theory6.15 Concept of Bond Order, Bond Length and Bond Energy6.16 Bonding in Some Homonuclear Diatomic Molecules6.17 Heteronuclear Diatomic Molecules6.18 Elementary Idea of Metallic Bonding6.19 Weak Forces6.20 Interactions between Ions and Covalent Molecules 7. Chemical Energetics7.1 Fundamentals of Thermodynamics7.2 The Zeroth Law of Thermodynamics7.3 Energy of the Thermodynamic System7.4 The First Law of Thermodynamics7.5 Calculation of Work Done in Different Processes7.6 Enthalpy or Heat Content,7.7 Expansion and Compression of an Ideal Gas7.8 Joule–Thomson Effect and Inversion Temperature7.9 Calorimetry7.10 Thermochemistry7.11 Thermochemical Equations7.12 Laws of Thermochemistry7.13 Enthalpies of Different Types of Reactions7.14 Bond Enthalpy and Bond Dissociation Enthalpy7.15 Spontaneity7.16 Carnot Cycle7.17 Entropy and Spontaneity7.18 Gibbs Energy and Spontaneity7.19 Second Law of Thermodynamics7.20 Gibbs Energy Change and Equilibrium7.21 Third Law of Thermodynamics 8. Solutions8.1 Type of Solutions8.2 Solubility8.3 Effect of Nature of Solute and Solvent8.4 Effect of Temperature on Solubility8.5 Effect of Pressure on Solubility of Gases8.6 Different Methods for Expressing Concentration of Solution8.7 Vapor Pressure of Solutions8.8 Enthalpy of Solution8.9 Ideal Solutions8.10 Non-Ideal Solutions8.11 Colligative Properties and Determination8.12 Abnormal Molar Masses and van ’t Hoff Factor 9. Chemical Equilibrium9.1 Physical Equilibria9.2 Chemical Equilibria – Dynamic Equilibrium9.3 Law of Chemical Equilibrium and Equilibrium9.4 Homogeneous and Heterogeneous Equilibria9.5 Applications of Equilibrium Constants9.6 Gibbs Energy Change and Chemical Equilibrium9.7 Simultaneous Equilibrium9.8 Le Chatelier’s Principle and Factors Affecting Equilibria 10. Ionic Equilibrium10.1 Weak and Strong Electrolytes10.2 Ionization of Electrolytes10.3 Concepts of Acids and Bases10.4 Acid–Base Equilibria and Ionization Constants10.5 Relative Strength of Acids and Bases10.6 Ionization of Polyprotic Acids10.7 Factors Affecting Acid Strength10.8 Acid–Base Neutralization – Formation of Salts10.9 pH Calculation of Single Monobasic Acid or Monoacidic Base10.10 pH Calculation of a Mixture of Two Acids or Bases10.11 pH Calculation for Polyprotic Acids10.12 Hydrolysis of Salts and pH of Their Solutions10.13 Buffer Solutions10.14 Acid–Base Titrations10.15 Theory of Indicators10.16 Solubility Equilibria of Sparingly Soluble Salts10.17 Preferential Precipitation of Salts10.18 Applications of Solubility Product 11. Electrochemistry11.1 Electrochemical Cells11.2 Electrode Potential11.3 Measurement of Electrode Potential11.4 Thermodynamics of a Cell11.5 Nernst Equation11.6 Calculation of °cell11.7 Types of Electrodes11.8 Concentration Cells 11.9 Electrolytic Cells and Electrolysis11.10 Applications of Electrolytic Process11.11 Batteries11.12 Electrical Conductance11.13 Conductance in Solutions of Electrolytes11.14 Conductometric Titrations 12. Chemical Kinetics12.1 Rate of a Chemical Reaction12.2 Factors Influencing Rate of a Reaction12.3 Differential Rate Expression and Rate Constant12.4 Elementary and Complex Reactions12.5 Molecularity of a Reaction12.6 Order of a Reaction12.7 Calculations of Order and Molecularity Based on Reaction Mechanisms12.8 Pseudo Order Reactions12.9 Integrated Rate Equations12.10 Half-Life of Reactions and Radioactivity12.11 Derivation of Rate Laws for Complex12.12 Reactions Using Integrated Rate Equations12.13 Effect of Temperature – Arrhenius Theory12.14 Effect of Catalyst12.15 Collision Theory 13. Surface Chemistry13.1 Adsorption13.2 Factors Affecting Adsorption13.3 Adsorption Isotherms13.4 Some Applications of Adsorption13.5 Catalysis13.6 Types of Catalytic Reactions13.7 Theory of Heterogeneous Catalysis13.8 Shape-Selective Catalysis by Zeolites13.9 Enzyme Catalysis13.10 Catalysts in Industry13.11 Colloids13.12 Preparation of Colloids13.13 Purification of Colloidal Solutions13.14 Properties of Colloidal Solutions13.15 Coagulation or Precipitation and Hardy–Schulze Rule13.16 Protection of Colloids13.17 Emulsions13.18 Role of Colloids in Natural Phenomena and in Industry 14 Nuclear Chemistry14.1 Radioactivity14.2 Structure of Atom14.3 Stability of Nucleus14.4 Modes of Radioactive Decay14.5 Decay Mechanism in Neutron-Rich and Neutron-Poor Nuclides14.6 Binding Energy and Nuclear Stability14.7 The Kinetics of Radioactive Decay14.8 Radioactive Equilibrium14.9 Activity of Radioactive Substances, Detection and Units of Radioactivity14.10 Natural vs. Induced Radioactivity14.11 Transmutation14.12 Nuclear Reactions14.13 Biological Effects of Radiation14.14 Applications of Radioactivity Solved Objective Questions from Previous Year PapersReview QuestionsNumerical ProblemsAdditional Objective QuestionsAnswersAppendix AAppendix BJEE (Advanced) 2019 PaperIndex